From the Super Mario Wiki
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Super Mario series
Super Mario World
Big Steelies first appear in the final battle with Bowser in Super Mario World. He drops these from his Koopa Clown Car. Mario or Luigi can jump over them to avoid getting hit. Mario or Luigi can also spin jump on them without getting hurt. It can be destroyed if Mario or Luigi uses his sliding cape attack against it using a Cape Feather, but it will show a glitched sprite.
Super Mario 64
Super Mario Maker
Super Mario World television series
In the Super Mario World episode "Send in the Clown", King Koopa attempts to defeat Mario in one scene by dropping a Big Steely on him, which Mario dodges. King Koopa, with the same method, is shown dropping a Big Steely after Yoshi hits him with his Mechakoopas. Mario, however, uses a golf club and knocks the Big Steely at him.
Super Smash Bros. Melee
Mario & Luigi: Bowser's Inside Story
In Mario & Luigi: Bowser's Inside Story, Big Steelies, referred to generically as "iron balls," appear in multiple locations. In Cavi Cape, Bowser must punch a falling one in order to knock it into a button. Later, Midbus crushes Bowser with a massive one, prompting Mario and Luigi to visit the Arm Center one last time. There is also a Hammer called the Iron Ball Hammer, which sometimes causes one to fall onto a random enemy after an "Excellent" rating is achieved.
Names in other languages