From the Super Mario Wiki
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Huge is a status effect from the game Paper Mario: The Thousand-Year Door. The Power Punch item gives the user this status effect. As its name implies, any character that is Huge will grow tremendously, boosting their Attack power by two for two turns. The indicator for this status effect is a large blushing face that takes up the entire indicator box. The character's voice and sound effects also deepen when Huge.
Some X-Nauts carry potions that can make them Huge.