From the Super Mario Wiki
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Sugar is an ingredient in Paper Mario. Princess Peach finds the ingredient in the kitchen of her castle, and must use it to bake a cake for Gourmet Guy. The Sugar is placed on the wooden table in the back of the kitchen in between the Flour and the Salt. After giving Gourmet Guy his cake, he reveals the location of the next imprisoned Star Spirit and agrees to not tell Bowser that Peach has escaped from her room.
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