From the Super Mario Wiki
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Sugar is an ingredient found in the game Paper Mario. Princess Peach found the ingredient in the kitchen of her castle and used it to bake a cake for Gourmet Guy. After giving the large Shy Guy the delicious bribe, Gourmet Guy revealed to Peach the location of the next imprisoned Star Spirit and agreed to not tell Bowser that Peach escaped from her room. It is placed on the wooden table in the back of the kitchen in between Flour and Salt.
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