From the Super Mario Wiki
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A Black Apple is an item in Super Paper Mario. It restores one HP and cures poison. It can be found on a tree in Overthere Stair. The Black Apple is also the cure for Princess Peach after she eats the Golden Apple. The Black Apple is mentioned to taste bad, and Peach is very irate over the fact that her friends forced her to eat it. The Black Apple is also known as the "taboo fruit."