From the Super Mario Wiki
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Petilil is a Grass-type Pokémon that first appeared in Pokémon Black and White. It evolves to Lilligant by having it hold a Sun Stone. In Super Smash Bros. for Nintendo 3DS, it appears as an enemy in the Smash Run Mode, and attacks by using Sleep Powder, which does not do any damage but will temporarily put the player to sleep. Otherwise, Petilil does minor damage if run into and does not have much health.
Super Smash Bros. for Nintendo 3DS Trophy information